Synthesis and crystal structure of [azido-bis(cis-1,2-diaminocyclohexane)copper(II)] chloride trihydrate-Reference-Cited by-同舟云学术

Synthesis and crystal structure of [azido-bis(cis-1,2-diaminocyclohexane)copper(II)] chloride trihydrate

Published:2018-03-12 Issue:3-4 Volume:73 Page:259-263
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Nawaz Sidra¹,Monim-ul-Mehboob Muhammad²,Tahir Muhammad Nawaz³,Hussain Irshad⁴,Habib-ur-Rehman ⁴,Hussain Syed Zajif⁴,Ahmad Saeed⁵

Affiliation:

1. Department of Chemistry , University of Engineering and Technology , Lahore 54890 , Pakistan

2. Department of Chemistry , Government Dyal Singh College , Lahore , Pakistan

3. Department of Physics , University of Sargodha , Sargodha , Pakistan

4. Department of Chemistry , SBA School of Science and Engineering , Lahore University of Management Sciences , Lahore 54792 , Pakistan

5. Department of Chemistry , College of Sciences and Humanities , Prince Sattam bin Abdulaziz University , Al-Kharj 11942 , Saudi Arabia

Abstract

Abstract A new copper(II) complex containing cis-1,2-diaminocyclohexane (Dach) and azide as ligands, [Cu(Dach)2(N3)]Cl · 3H2O (1), was prepared and characterized by IR spectroscopy, thermal analysis and X-ray crystallography. The structure of 1 consists of a complex cation, [Cu(Dach)2(N3)]+, a chloride counter-ion and three water molecules. The coordination environment of the copper(II) atom in 1 is distorted square pyramidal attained by four nitrogen atoms of cis-1,2-diaminocyclohexane molecules and an azide ion. Thermogravimetric and differential scanning calorimetric analyses validated the molecular formula of complex 1.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2017-0175/pdf

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1. DFT Calculations and SEM–EDX Analysis of Copper(II)-Azide Complexes; [Cu(en)2(N3)2] and [Cu(Tmen)(N3)2]2 (Tmen = N,N,N',N'-Tetramethylethylenediamine);Russian Journal of Physical Chemistry B;2021-08

2. DFT Analysis of Copper(II) Complexes of cis-1,2-Diaminocyclohexane (Dach), [Cu(Dach)2(N3)]Cl·3H2O and [Cu(Dach)2-Ag(CN)2-Cu(Dach)2][Ag(CN)2]3;Journal of Structural Chemistry;2019-04