Towards a better understanding of the oxide film growth mechanism in E110 zirconium alloy under high-temperature oxidation in steam

Author:

Rozhnov Andrey B.1,Alsheikh Hannanh1,Nikulin Sergey A.1,Belov Vladislav A.1,Li Elina V.1,Koteneva Maria V.1

Affiliation:

1. National University of Science and Technology “MISIS”, Leninsky Prospekt 4, 119049, Moscow, Russia

Abstract

AbstractHigh-temperature oxidation of E110 (Zr-1%Nb) zirconium alloy in steam at Т = 1100°C to various degrees has been carried out. Based on the studies of morphology and microstructure of the oxide film and metal, as well as on review of previously published results, the mechanism of alloy oxidation has been proposed, which includes oxide thickening close to the oxide/metal interface, growth of the thickened areas and their conversion into nodules, growth of the nodules and crowning of the metal surface (white spots), clustering of nodules under the formed oxide, formation of a double (white on the surface) oxide film and delamination of the oxide upper layer.

Publisher

Walter de Gruyter GmbH

Subject

General Materials Science,General Chemical Engineering,General Chemistry

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