Study on the thermal stability and smoke suppressant effect of polyurethane foam modified by ammonium lignosulfonate-Reference-Cited by-同舟云学术

Study on the thermal stability and smoke suppressant effect of polyurethane foam modified by ammonium lignosulfonate

Published:2023-08-18 Issue:1 Volume:39 Page:15-31
ISSN:0930-777X
Container-title:International Polymer Processing
language:en
Short-container-title:

Author:

Zhang Xu¹²,Yuan Dehe¹²,Sun Simiao¹²,Wang Zhi¹²,Xie Hua¹²,Su Zhanpeng³

Affiliation:

1. Liaoning Key Laboratory of Aircraft Fire Explosion Control and Reliability Airworthiness Technology , Shenyang Aerospace University , Shenyang 110136 , China

2. School of Safety Engineering , Shenyang Aerospace University , Shenyang 110136 , China

3. International Engineering College , Shenyang Aerospace University , Shenyang 110136 , China

Abstract

Abstract The modified polyurethane foam (PUF) with ammonium lignosulfonate was prepared by one-step water foaming method. The effects of ammonium lignosulfonate on its thermal stability and smoke suppression were investigated by thermogravimetric analysis, pyrolysis kinetics analysis, smoke density (Ds) and smoke toxicity analysis. The results showed that the addition of 15 % ammonium lignosulfonate (PUFA15) had the lowest mass loss of PUFs and the highest integral programmed decomposition temperature (870.8 °C). Its activation energy was the highest according to the Flynn-Wall-Ozawa method (110.1 kJ/mol), Kissinger method (181.1 kJ/mol), Starnk method (106.3 kJ/mol) and Coats-Redfern method (149.7 kJ/mol). In addition, PUFA15 had the lowest Ds (34.43) and the highest transmittance (66.74). This indicated that PUFA15 had good thermal stability and smoke suppression properties. The research results had a reference value for exploring the production of environmentally friendly PUF by biomass modification.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Industrial and Manufacturing Engineering,Polymers and Plastics,General Chemical Engineering

Link

https://www.degruyter.com/document/doi/10.1515/ipp-2023-4378/pdf

Reference24 articles.

1. Abid, A., Nicolas, B., Isabelle, Z., and Slimane, G. (2020). Production and characterization of rigid polyurethane foam by oxypropylation of organosolv lignin extracted from exhausted olive pomace. J. Polym. Res. 27: 4997–5004, https://doi.org/10.1007/s10965-020-02228-9.

2. Coats, A.W. and Redfern, J.P. (1964). Kinetic parameters from the thermogravimetric data. Nature 201: 68–69, https://doi.org/10.1038/201068a0.

3. Gao, L.P., Zheng, G.Y., Zhou, Y.H., Hu, L.H., and FengG, D. (2015). Improved mechanical property, thermal performance, flame retardancy and fire behavior of lignin-based rigid polyurethane foam nanocomposite. J. Therm. Anal. Calorim. 120: 1311–1325, https://doi.org/10.1007/s10973-015-4434-2.

4. Gondaliya, A. and Nejad, M. (2021). Lignin as a partial polyol replacement in polyurethane flexible foam. Molecules 26: 2302, https://doi.org/10.3390/MOLECULES26082302.

5. Guida, M.Y., Bouaik, H., El Mouden, L., Moubarik, A., Aboulkas, A., El harfi, K., and Hannioui, A. (2017). Utilization of starink approach and avrami theory to evaluate the kinetic parameters of the pyrolysis of olive mill solid waste and olive mill wastewater. J. Adv. Chem. Eng. 7: 1–8, https://doi.org/10.4172/2090-4568.1000155.

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Fabrication of expandable graphite and soybean oil-based synergistic modified polyurethane foam with improved thermal stability and flame retardant properties;International Polymer Processing;2023-11-28