Exploration of the thermal and mechanical characteristics of polymethyl methacrylate-based copolymers: implications for wind turbine blades applications
Author:
Xue Huimin12, Li Chun2, Sui Jiayang2, Liu Lifei2, Ma Xiaokun3, Liang Chenhong3, Zhao Weizhen2
Affiliation:
1. College of Chemical Engineering, Shenyang University of Chemical technology , Shenyang , Liaoning 110000 , P.R. China 2. Beijing Key Laboratory of Ionic Liquids Clean process, CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences , Beijing 100190 , P.R. China 3. New Materials Research Center, Zhengzhou Institute of Emerging Industrial technology , Zhengzhou Henan 450000 , P.R. China
Abstract
Abstract
Wind turbine (WT) blade fabrication typically employs thermosetting resins, whose recycling challenges post-retirement have resulted in environmental pressures. Thus, there is an urgent need to develop a low-viscosity, high-performance, and recyclable material with excellent mechanical properties that is compatible with WT fabrication processes, serving as a viable alternative to traditional epoxy resins. Poly(methyl methacrylate) (PMMA) resin is considered a promising candidate for replacing epoxy resins. However, the mechanical properties of PMMA still require improvement. In this study, we investigated the effects of introducing copolymerized monomers on the comprehensive performance of PMMA resin without affecting its viscosity, examining the influence of these copolymerized monomers on the material’s thermal and mechanical properties. Meanwhile, the mechanical properties of the synthesized PMMA-based copolymers were compared with those of blade-specific epoxy resin (WD0135). The results revealed that compared to WD0135, the flexural strength and modulus of the prepared PMMA copolymers significantly increased to 96.6 and 3158.6 MPa, respectively, with a tensile strength reaching 74.2 MPa. Consequently, this series of PMMA-based resins demonstrates immense potential for large-scale material part fabrication via casting techniques.
Publisher
Walter de Gruyter GmbH
Reference36 articles.
1. Atabaki, F., Shokrolahi, A., and Pahnavar, Z. (2018). Methyl methacrylate based copolymers and terpolymers: preparation, identification, and plasticizing capability for a poly(methyl methacrylate) used in aviation. J. Appl. Polym. Sci. 135: 46603, https://doi.org/10.1002/app.46603. 2. Ali, U., Karim, K., and Buang, N.A. (2015). A review of the properties and applications of poly(methyl methacrylate) (PMMA). Polym. Rev. 55: 678–705, https://doi.org/10.1080/15583724.2015.1031377. 3. Bai, X.T., Zhang, C.L., Liu, B., Jiang, C.M., and Mu, J.X. (2012). Synthesis and thermal stability of hybrid polymers using UV photopolymerization based on polyhedral oligomeric silsesquioxanes. High Perform. Polym. 24: 274–281, https://doi.org/10.1177/0954008312436705. 4. Chat, K., Maksym, P., Kamiński, K., and Adrjanowicz, K. (2022). Stereoregulation, molecular weight, and dispersity control of PMMA synthesized via free-radical polymerization supported by the external high electric field. Chem. Commun. 58: 5653–5656, https://doi.org/10.1039/D2CC01186G. 5. Cascione, M., Matteis, V.D., Pellegrino, P., Albanese, G., Giorgi, M.L.D., Paladini, F., Corsalini, M., and Rinaldi, R. (2021). Improvement of PMMA dental matrix performance by addition of titanium dioxide nanoparticles and clay nanotubes. Nanomaterial 11: 2027, https://doi.org/10.3390/nano11082027.
|
|