Metal Tetrahydroborates and Tetrahydroborato Metalates, 17 / Bonding in Cadmium Bis(tetrahydroborate), and the Reaction with Lithium Tetrahydroborate-Reference-Cited by-同舟云学术

Metal Tetrahydroborates and Tetrahydroborato Metalates, 17 / Bonding in Cadmium Bis(tetrahydroborate), and the Reaction with Lithium Tetrahydroborate

Published:1990-11-01 Issue:11 Volume:45 Page:1482-1486
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Nöth Heinrich¹,Thomann Martina¹

Affiliation:

1. Institute of Inorganic Chemistry, University of Munich, Meiserstraße 1, D-8000 München 2, Fed. Rep. Germany

Abstract

Cadmium bis(tetrahydroborate) has been prepared from dimethyl cadmium and H3B · THF in tetrahydrofuran. Low temperature 113Cd NMR spectra recorded for THF, monoglyme and diglyme solutions show a septet with 1J(113Cd1H) = 273 Hz. This proves that the BH4⁻ groups are bound to the metal centre via triple hydride bridges. Reaction of Cd(BH4)2 with LiBH4 yields LiCd(BH4)3 quantitatively in diglyme solution.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1990-1103/pdf

Cited by 5 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Metal Borohydrides beyond Groups I and II: A Review;Materials;2021-05-14

2. ChemInform Abstract: Metal Tetrahydroborates and Tetrahydroborato Metalates. Part 17. Bonding in Cadmium Bis(tetrahydroborate), and the Reaction with Lithium Tetrahydroborate.;ChemInform;2010-08-23

3. Methylzinc tetrahydroborate: physical and chemical properties and crystal structure at low temperature;Journal of the Chemical Society, Dalton Transactions;1996

4. Metal Tetrahydroborates and Tetrahydroborato Metalates. 20. Reactions of Cadmium Tetrahydroborate with Alcoholates and Phenolates ‐ X‐ray Structure of [MeCd(OCMe 3 )] 4;Chemische Berichte;1995-09

5. Metal Tetrahydroborates and Tetrahydroboratometalates, 18 [1] Studies on the Formation of Cadmium(II)-tetrahydroborates with Tetrahydroborate and Iodide;Zeitschrift für Naturforschung B;1994-01-01