Darstellung und Kristallstruktur der Verbindungen SEPdP (SE = Seltenerdelement) / Preparation and Crystal Structure of SEPdP Compounds (SE = Rare Earth Element)

Author:

Johrendt Dirk1,Mewis Albrecht1

Affiliation:

1. Institut für Anorganische Chemie der Universität Köln, Greinstraße 6, D-5000 Köln 41

Abstract

The new compounds SEPdP (SE = La—Gd), which were prepared by heating the elements, crystallize with a modified Ni2In-type structure. The phosphides of SE = Dy—Lu attain the orthorhombic TiNiSi-type structure. A comparison of the cell volumes suggests that europium has intermediate valence in EuPdP.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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