Aminosubstituierte Organoindiumchloride: [i-Pr(Cl)InN(H)t-Bu]2 und [Mes(Cl)InN(SiMe3)2]2 / Amino-Substituted Organoindium Chlorides: [i-Pr(Cl)InN(H)t-Bu]2 and [Mes(Cl)InN(SiMe3)2]2

Abstract

The reactions of isopropyl indium dichloride (1) with LiN(H)t-Bu and of mesityl indium chloride (2) with NaN(SiMe3)2 lead to compounds [i-Pr(Cl)InN(H)t-Bu]2 (3) and [Mes(Cl)InN(SiMe3)2]2 (4), respectively. 3 forms dimers in solution and in the solid state, while the monomer is the predominate species of 4 in solution. 3 crystallizes in 2 isomers. The X-ray analysis of one isomer of 3 is reported.