Neue A4B3-Moleküle: P3SbS3, P4S2Te und P4STe2 / New A4B3 Molecules: P3SbS3, P4S2Te and P4STe2

Author:

Baldus Hans Peter1,Blachnik Roger1

Affiliation:

1. Anorganische Chemie, Universität Osnabrück, Barbarastraße 7, D-4500 Osnabrück

Abstract

The new molecules P3SbS3, P4S2Te und P4STe2 were extracted with CS2 from mixtures of S. Sb and P4S3, and P, S and Te samples respectively, which were previously molten and then annealed for several days. In the P3SbS3 molecules the apical phosphorus position of P4S3 is substituted by antimony. In the molecules P4STe2 and P4S2Te one or two of the sulphur bridges are substituted by tellurium. X-ray and 31P NMR data of the compounds are given.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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