Elektronentransfer und Ionenpaar-Bildung, 8 [1] 107,109Ag ENDOR-Kopplungen und Redox-Verhalten des Radikal-Kontaktionenpaares aus Bis(triphenyIphosphino)silber(I)-Kation und 3,5-Di(tert-butyl)-o-benzosemichinon-Anion / Electron Transfer and Ion Pairing, 8 [1] 107'109Ag ENDOR Couplings and Redox Behaviour of the Radical Contact Ion Pair from Bis(triphenylphosphino)silver(I) Cation and 3,5-Di(tert-butyl)-o-benzosemiquinone Anion-Reference-Cited by-同舟云学术

Elektronentransfer und Ionenpaar-Bildung, 8 [1] 107,109Ag ENDOR-Kopplungen und Redox-Verhalten des Radikal-Kontaktionenpaares aus Bis(triphenyIphosphino)silber(I)-Kation und 3,5-Di(tert-butyl)-o-benzosemichinon-Anion / Electron Transfer and Ion Pairing, 8 [1] 107'109Ag ENDOR Couplings and Redox Behaviour of the Radical Contact Ion Pair from Bis(triphenylphosphino)silver(I) Cation and 3,5-Di(tert-butyl)-o-benzosemiquinone Anion

Published:1988-10-01 Issue:10 Volume:43 Page:1247-1252
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Bock H¹,Hierholzer B¹,Jaculi D¹

Affiliation:

1. Chemische Institute der Universität Frankfurt, Niederurseier Hang, D-6000 Frankfurt/Main

Abstract

For the first time, 107,109Ag ENDOR measurements in solution are reported. In addition, the formation of the known paramagnetic contact ion pair [Ag⊕(PR3)2(R2H2C6O2 ·⊖] on reduction of 3,5-di(tert-butyl)-o-benzoquinone in THF solution containing soluble silver salts and triphenylphosphine is studied by cyclic voltammetry.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1988-1006/pdf

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