Elektronentransfer und Ionenpaar-Bildung, 7 [1, 2] Kontakt-Ionenpaare Schwefel enthaltender Radikalanionen / Electron Transfer and Ion Pairing, 7 [1, 2] Contact Ion Pairs of Sulfur-Containing Radical Anions-Reference-Cited by-同舟云学术

Elektronentransfer und Ionenpaar-Bildung, 7 [1, 2] Kontakt-Ionenpaare Schwefel enthaltender Radikalanionen / Electron Transfer and Ion Pairing, 7 [1, 2] Contact Ion Pairs of Sulfur-Containing Radical Anions

Published:1988-10-01 Issue:10 Volume:43 Page:1240-1246
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Bock Hans¹,Hänel Peter,Herrmann H.-F,Dieck Heindirk torn²

Affiliation:

1. Chemische Institute der Universitäten Frankfurt Martin-Luther-King-Platz 6, D-2000 Hamburg 13. FRG

2. Niederurseier Hang, D-6000 Frankfurt (M) 50 und Hamburg Martin-Luther-King-Platz 6, D-2000 Hamburg 13. FRG

Abstract

The structurally different radical anions M⊖ of peralkylated 1-sila-2,5-diazacyclopentane-3,4-dithione and of tetrakis(isopropylthio)-p-benzoquinone are generated by reduction with potassium/2.2.2-cryptand under aprotic conditions in THF solution. On addition of Li⊕B(C6H5)4 ⊖, both form hitherto elusive sulfur-containing contact ion pairs, which are characterized by their ESR/ENDOR spectra.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1988-1005/pdf

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