Zur Polymorphie von TbCI3/ Polymorphism of TbCl3-Reference-Cited by-同舟云学术

Zur Polymorphie von TbCI3/ Polymorphism of TbCl3

Published:1988-08-01 Issue:8 Volume:43 Page:1023-1028
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Gunsilius Harald¹,Borrmann Horst¹,Simon Arndt¹,Urland Werner²

Affiliation:

1. Stuttgart, Max-Planck-Institut für Festkörperforschung, Heisenbergstraße 1, D-7000 Stuttgart 80

2. Hannover, Institut für Anorganische Chemie der Universität, Callinstraße 9, D-3000 Hannover

Abstract

Abstract 3 different modifications of TbCl3 were synthesized. TbCl, (UCl3-type), probably in a metastable state, crystallizes in space group P63/m with a = 737.63(2) pm, c = 405.71(2) pm and Z - 2. TbCl3 (PuB3-type) crystallizes in space group Cmcm with a = 384.71(6) pm, b = 1177.37(7) pm. c = 851.77(4) pm and Z = 4. h-TbCl3, the high temperature phase being stable above 790 K. crystallizes in space group P42/mnm with a = 642.51(4) pm, c = 1177.14(18) pm and Z = 4.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1988-0819/pdf

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