Darstellung und Kristallstruktur von (PhN3)2C6H4[(OH)Ni(PhN 3H)2C6H4]2 · 2THF, einem dimeren Ni(II)-Komplex mit einem überbrückenden Bistriazenido-Liganden-Reference-Cited by-同舟云学术

Darstellung und Kristallstruktur von (PhN3)2C6H4[(OH)Ni(PhN 3H)2C6H4]2 · 2THF, einem dimeren Ni(II)-Komplex mit einem überbrückenden Bistriazenido-Liganden

Published:1988-09-01 Issue:9 Volume:43 Page:1174-1178
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Hörner Manfredo¹,Fenner Herton¹,Hiller Wolfgang²,Beck Johannes³

Affiliation:

1. Universidade Federal de Santa Maria, Departamento de Quimica, 97.111 Santa Maria - RS, Brasil

2. Institut für Anorganische Chemie der Universität Tübingen, Auf der Morgenstelle 18, D-7400 Tübingen, BRD

3. Institut für Anorganische Chemie der Universität Karlsruhe. Engesserstraße, D-7500 Karlsruhe, BRD

Abstract

Abstract (PhN3)2C6H4[(OH)Ni(PhN3H)2C6H4]2 · 2THF is obtained by the reaction of [(PhN3)2C6H4]Na2 with aqueous NiCl2. It crystallizes from tetrahydrofuran/hexane in the monoclinic space group P21/n, with a = 1574.6(3), b = 2498.5(2), c = 1629.2(2) pm, β = 93.909(3)°, and Z = 4. The Ni atoms are bridged by the bis(phenyltriazenidyl)benzene group and two hydroxyl groups. Two neutral bis(phenyltriazenyl)benzene groups chelate each Ni atom to complete the distorted coordination sphere.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1988-0915/pdf

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