Affiliation:
1. Abteilung II für Anorganische Chemie im Eduard-Zintl-Institut der Technischen Hochschule Darmstadt
Abstract
KSbSe2, prepared by heating a mixture of the elements in a silica tube, crystallizes triclinic with the following constants
a = 1248.1(5) pm, α = 103.16(5)°,
b = 644.5(5) pm, β = 99.27(5)°,
c = 645.0(5) pm, γ = 99.44(5)°.
There are SbSe2
--chains, formed by Ψ-tri-gonal bipyramids, which are connected by sharing edges.
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