Mass Spectral Fragmentation Pattern of Ν,N′ -Diphenylformamidines

Author:

Keats Neil G.1,Rockley Jean E.1,Summers Lindsay A.1

Affiliation:

1. Department of Chemistry, The University of Newcastle, 2308, New South Wales, Australia

Abstract

The base peaks in the mass spectra of Ν,N′-diphenylformamidine, N,N′-di-(4-chlorophenyl)formamidine and N,N′-di-(3-chlorophenyl)formamidine are due to the molecular ions of aniline, 4-chloroaniline and 3-chloroaniline respectively. The species responsible for the base peaks are thought to be formed by rupture of the CH-NH bond with concomitant hydrogen migration.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Cited by 8 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Mass spectral fragmentation of tautomerizingN,N′-diarylbenzamidines;Journal of Mass Spectrometry;1999-09

2. The coordination chemistry of the amidine ligand;Coordination Chemistry Reviews;1994-07

3. Neue N-Arylsubstituierte 2,6-Difluorbenzamidine;Journal of Fluorine Chemistry;1991-12

4. General and theoretical aspects of amidines and related compounds;Amidines and Imidates (1991);1991-01

5. Mass spectra of amidines and related compounds;Amidines and Imidates (1991);1991-01

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