Ni(II) Complexes with bis(β-Acylvinyl)amines and (8-Quinolyl-β-acylvinyl)amines

Author:

Dabrowski Janusz1,Krówczyński Adam1

Affiliation:

1. Institute of Organic Chemistry, Polish Academy of Sciences, 00-961 Warsaw, Poland

Abstract

The title complexes have been obtained and shown by elemental analysis, IR and PMR spectra to be octahedral. The trans structure has been assigned to bis(β-acylvinyl)amine complexes based on magnetic equivalence of geminal methyl groups in appropriately substituted representatives of this group of compounds. The (8-quinolyl-β-acylvinyl)-amine complexes may have either trans or s-cis (meso) configuration.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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