Thermodynamics of Lead(II) Halide Complex Formation in Calcium Nitrate Tetrahydrate -Acetamide Melts-Reference-Cited by-同舟云学术

Thermodynamics of Lead(II) Halide Complex Formation in Calcium Nitrate Tetrahydrate -Acetamide Melts

Published:2001-12-01 Issue:12 Volume:56 Page:832-836
ISSN:1865-7109
Container-title:Zeitschrift für Naturforschung A
language:en
Short-container-title:

Author:

Gadzuric S. B.¹,Zsigrai I. J.¹,Nikolic R. M.²

Affiliation:

1. Institute of Chemistry, Faculty of Science, University of Novi Sad, Trg D. Obradovica 3, 21000 Novi Sad, Yugoslavia

2. Institute of Nuclear Sciences “Vinca”, PO Box 522, 11000 Belgrade, Yugoslavia

Abstract

Abstract The complex formation between lead(II) ions and chloride and bromide ions in melts of C a(N 03) 2 • 4 H2O • αCH3CONH2 has been studied at different temperatures between 30 and 70 °C. The formation constants of the complexes PbX+ and PbX2 (X = Cl, Br) were determined from em f measurements by means of Ag/AgX electrodes. The dependence of the formation constants for PbCl+ on the solvent melt composition has been analysed. The thermodynamic parameters ΔH0 11 and ΔS0 11 for PbX+ complex formation have been estimated. The parameters are compared with the literature data for the same process in dilute aqueous solutions and in some hydrated and anhydrous salt melts.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Link

https://www.degruyter.com/document/doi/10.1515/zna-2001-1206/pdf

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Specific Conductivities and Viscosities of 0.1LiNO3 + 0.9[xCH3CONH2 + (1 – x)CO(NH2)2] as Functions of Mole Fraction, x, and Temperature;Journal of Chemical & Engineering Data;2012-11-27

2. Electrical Conductivity and Phase Transitions of Calcium Nitrate + Ammonium Nitrate + Water Mixtures;Journal of Chemical & Engineering Data;2010-04-05