Redox Potentials of Samarium and Europium in Molten Lithium Chloride

Author:

Novoselova Alena1,Shishkin Vladimir1,Khokhlov Vladimir1

Affiliation:

1. 1Institute of High-Temperature Electrochemistry, 20 S. Kovalevskaya Str., 620219, Ekaterinburg,Russia

Abstract

Abstract The samarium (III)/(II) and europium (III)/(II) redox potentials in molten lithium chloride were measured using the direct potentiometric method in the temperature range from 923 to 1094 K. Glassy carbon was used as the indifferent working electrode, and the standard chlorine electrode as a reference. The total concentration of rare-earth chlorides dissolved in molten lithium chloride did not exceed 4.5 mol%.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

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