Halogen NQR Studies in Certain Mercuric Halide-Polyether Complexes

Author:

Indumathy S.1,Sridharan K. R.1,Ramakrishna J.1,Wulfsberg G.2

Affiliation:

1. Department of Physics, Indian Institute of Science, Bangalore 560 012, India

2. Department o f Chemistry, M iddle Tennessee State University, Murfreesboro TN 37132, USA

Abstract

The temperature variation of 35Cl and 81Br NQR frequencies are reported for mercuric chloride · triethylene glycol dimethyl ether (HgCl2 · triglyme), mercuric chloride · diethylene glycol dimethyl ether (HgCl2 · diglyme), and mercuric bromide · diethylene glycol dimethyl ether (HgBr2 · diglyme). The frequencies have been assigned to the appropriate halogens using molecular models which take into account the various intra- and inter-molecular interactions in the solid state. The observed temperature variation of the NQR frequencies, in the range 77 -300 K. has been analysed using the two torsional mode analysis in the framework of the Bayer-Kushida-Brown method with Tatsuzaki’s correction to obtain the torsional frequencies and their average temperature coefficients.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Cited by 5 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. STRUCTURAL STUDIES OF POLYETHER COORDINATION TO MERCURY(II) HALIDES: CROWN ETHER VERSUS POLYETHYLENE GLYCOL COMPLEXATION;Journal of Coordination Chemistry;1993-08

2. STRUCTURAL STUDIES OF POLYETHER COORDINATION TO MERCURY(II) HALIDES: CROWN ETHER VERSUS POLYETHYLENE GLYCOL COMPLEXATION;Journal of Coordination Chemistry;1993-07

3. References;Nuclei Zn - Bi, Diagrams, Indexes

4. 23-153 - 23-238: C6H6BrN - C38H36Br3CuP2;Nuclei Zn - Bi, Diagrams, Indexes

5. References to Table 11;Landolt-Börnstein - Group III Condensed Matter

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