Affiliation:
1. Institut für Physikalische Chemie, Physikalische Chemie III, Technische Hochschule Darmstadt
Abstract
The temperature dependence of salts M(1)H(Cl3CCOO)2 and molecular compounds of trichloroacetic acid with amines and benzaldehydes, TCA · X, was studied,
The data fit rather well to the known dependence of the mean frequency shift Δ <v(35Cl)> on the pkadifference of X with respect to TCA. A linear relation is observed between the bleaching out temperature Tb of the 35Cl NQR lines and Δ <v(35Cl)> for M(1)H(Cl3CCOO)2 and for TCA · X, X = benzaldehydes.
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics
Cited by
14 articles.
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