Oscillatory Oxidation of Malonic Acid by Bromate-Reference-Cited by-同舟云学术

Oscillatory Oxidation of Malonic Acid by Bromate

Published:1973-12-01 Issue:11-12 Volume:28 Page:824-827
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Bornmann L.¹,Busse H.¹,Hess B.²,Riepe R.³,Hesse C.⁴

Affiliation:

1. Max-Planck-Institut für Ernährungsphysiologie, Dortmund -

2. Max-Planck-Institut für Ernährungsphysiologie, Dortmund

3. Institut für Spektrochemie und angewandte Spektroskopie, Dortmund

4. Institut für Ernährungswissenschaft, Universität Bonn

Abstract

In order to elucidate the reaction scheme of the oscillatory malonic acid-KBrO3system in sulphuric acid the products extracted from the reaction system by ether are analysed by gas chromatography and mass spectrometry. After 2 hours reaction time implying approx. 80 to 100 cycles malonic acid, monobromomalonic acid and dibromoacetic acid are identified in a relative ratio of about 1.0, 0.14 and 0.023.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1973-11-1223/pdf

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