Affiliation:
1. Institut für Anorganische und Analytische Chemie , Universität Münster , Corrensstrasse 30 , 48149 Münster , Germany
2. Department of Analytical Chemistry , Ivan Franko National University of Lviv , Kyryla i Mefodiya Street 6 , 79005 Lviv , Ukraine
Abstract
Abstract
The intermetallic scandium compounds Sc1.024Ir2In0.976 and Sc3Ir1.467In4 were synthesized by reactions of the elements in sealed tantalum ampoules at high temperature followed by annealing for crystal growth. Both structures were refined from single-crystal X-ray diffractometer data: MnCu2Al type,
F
m
3
‾
m
$Fm‾{3}m$
, a = 639.97(19) pm, wR2 = 0.0376, 41 F
2 values, seven variables for Sc1.024Ir2In0.976 and
P
6
‾
$P‾{6}$
, a = 769.99(5), c = 684.71(4) pm, wR2 = 0.0371, 967 F
2 values, 33 variables for Sc3Ir1.467In4. Sc1.024Ir2In0.976 is a new Heusler phase with a small homogeneity range due to Sc/In and In/Sc mixing. The structure of Sc3Ir1.467In4 is closely related to that of Sc3Rh1.594In4 and belongs to the large family of ZrNiAl superstructures. The striking structural motif is the ordered stacking of empty In6 and filled Ir@In6 prisms with Ir–In distances of 269 pm.
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