Affiliation:
1. Karlsruhe Institute of Technology (KIT), Institute for Applied Materials (IAM) , Herrmann-von-Helmholtz-Platz 1 , D-76344 Eggenstein-Leopoldshafen , Germany
Abstract
Abstract
Concerning the crystal structure of PbCN2 there exist two different descriptions in the literature, one based on the non-centrosymmetric structure, space group Pna21, another one on the centrosymmetric one in space group Pnma. To elucidate the conditions for their appearance, comprehensive preparative and structural investigations have been conducted which proved the existence of two distinct modifications of PbCN2. A detailed comparison of the two phases is provided. The growth conditions and crystallization processes of the two PbCN2 structures are reported with focus on the influence of the pH value on the products. Depending on the growth conditions several different morphologies arise, namely PbCN2 in needle-shaped and platelet-shaped crystals, as well as pompon-shaped and lance-shaped crystals.