Affiliation:
1. Institut für Anorganische Chemie, TU Bergakademie Freiberg , Leipziger Straße 29, 09599 Freiberg , Germany
Abstract
Abstract
New N-silylated phthalimides, succinimides, and 1,8-napthalimides were synthesised by reactions of the alkali imides with chlorosilanes in THF. Six different mono-, di-, tri- and tetra-iminosilanes of the type (CH3)4–n
Si(imide)
n
were obtained and the products analysed with 1H, 13C, 29Si NMR, and Raman spectroscopy. The molecular structures of four imidosilanes have been determined by single-crystal X-ray diffraction. A characteristic structural feature of the compounds is the fact that all intramolecular Si⋯O distances are significantly below the sum of the van-der-Waals radii of silicon and oxygen of 3.62 Å. Experimentally found values for Si⋯O distances range from 2.813 to 3.030 Å. However, there are no significant orbital interactions between silicon and oxygen atoms, as shown by quantum chemical analysis with AIM and NBO methods. The short Si⋯O distances in these molecules are caused by the geometry of the rigid imide group bound to the silicon atom, and there is no evidence for an increase of the coordination number of the Si atoms.
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