Synthesis and structure of the λ 6Si-silicate [Cs(18-crown-6)]2[Si(OSO2CH3)6]-Reference-Cited by-同舟云学术

Synthesis and structure of the λ 6Si-silicate [Cs(18-crown-6)]2[Si(OSO2CH3)6]

Published:2021-06-18 Issue:0 Volume:0 Page:
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Georg Isabelle¹,Bolte Michael¹,Wagner Matthias¹,Lerner Hans-Wolfram¹

Affiliation:

1. Institut für Anorganische Chemie, Goethe-Universität Frankfurt , Max-von-Laue-Straße 7, 60438 Frankfurt am Main , Germany

Abstract

Abstract The λ 6Si-silicate [Cs(18-crown-6)]2[Si(OSO2CH3)6] (1) was synthesized by treatment of Si2Cl6 with Cs[OSO2CH3] in the presence of 18-crown-6. Compound 1 is the first example of a λ 6Si-silicate with a methanesulfonate ligand. It was characterized by NMR spectroscopy and by single-crystal X-ray diffraction. The solid-state structure of 1 consists of discrete [Si(OSO2CH3)6]2– anions and two [Cs(18-crown-6)]+ cations (triclinic space group, P 1 ¯

$P\overline{1}$

, Z = 1).

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2021-0068/pdf

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