The Hyperfine Structure in the Rotational Spectrum of CuCl

Author:

Tiemann E.1,Hoeft J.1

Affiliation:

1. Institut für Molekülphysik der Freien Universität Berlin

Abstract

Abstract The hyperfine structure of the rotational transition J = 1 ← 0 of 63Cu35Cl in the ground vibrational state was observed. The analysis resulted in the following nuclear quadrupole coupling constants: 63Cu: e q0 Q= +16.08(20) MHz; 35Cl: eq0 Q = - 32.25(15) MHz. The influence of the small magnetic spin rotational coupling of both nuclei on the hyperfine spectrum is discussed.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Cited by 8 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Pure rotational spectroscopy;Rotational Spectroscopy of Diatomic Molecules;2003-04-10

2. Millimeter- and Submillimeter-Wave Spectra of CuF and AgF in the X1Σ+ Electronic Ground States;Journal of Molecular Spectroscopy;2001-09

3. Fourier Transform Emission Spectroscopy of CuCl;Journal of Molecular Spectroscopy;2001-03

4. Microwave spectra of metal chlorides produced using laser ablation;The Journal of Chemical Physics;1993-09

5. Hyperfine interaction in the E Ω=0+ state of CuCl;Chemical Physics Letters;1990-11

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