Affiliation:
1. Institut für Physikalische Chemie der Universität Frankfurt/M.
Abstract
The microwave spectrum of CF3CCl3 has been investigated in the region from 15 to 40 GHz. A least squares analysis of the rotational constants gave the following structural parameters:
dC–C= (1,5394 ± 0,001) A, dC–F= (1,330 ±0,001) A, dC-Cl = (1,7710 ± 0,0009) A,
∢ C—C—F = (109,55 ± 0,25) °, ∢ C—C—Cl= (109,55 ± 0,25) °.
The splitting of the torsional satellite may be explained by the theory of KOEHLER and DENNISON.
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics
Cited by
12 articles.
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