Novel Formulation of the Gibbs–Energy Change in Terms of Stoichiometrically Unique Response Reactions-Reference-Cited by-同舟云学术

Novel Formulation of the Gibbs–Energy Change in Terms of Stoichiometrically Unique Response Reactions

Published:1996-11-01 Issue:10-11 Volume:51 Page:1079-1083
ISSN:1865-7109
Container-title:Zeitschrift für Naturforschung A
language:en
Short-container-title:

Author:

Fishtik Ilie¹,Nagypál István²,Gutman Ivan²³

Affiliation:

1. Institute of Chemistry, Academy of Sciences of Moldova, 277028 Kishinev, str. Academiei 3, Republica Moldova

2. Institute of Physical Chemistry, Attila Jözsef University, H-6701 Szeged, P. O. Box 105, Hungary

3. on leave from Faculty of Science, University of Kragujevac, Kragujevac, Yugoslavia

Abstract

Abstract The equation for the change of Gibbs energy in complex chemical systems is reformulated in terms of the newly conceived response reactions (RERs). The present formulation has the remarkable property of being unique: the composition of the species unequivocally determines the response reactions and via them the change of the Gibbs energy of the system. Furthermore, it enables one to reinterpret and rationalize some basic concepts of chemical thermodynamics, as coupling between reactions, sensitivity coefficients, etc.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Link

https://www.degruyter.com/document/doi/10.1515/zna-1996-10-1104/pdf

Cited by 4 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. The Stoichiometric Uniqueness of Multiple Chemical Reaction Systems in Chemical Thermodynamics, Kinetics and Catalysis – Contributions of Professor Ilie Fishtik;Chemistry Journal of Moldova;2020-12

2. A thermodynamic approach to the systematic elucidation of unique reaction routes in catalytic reactions;Chemical Engineering Science;2000-10

3. Enumeration and discrimination of mechanisms in heterogeneous catalysis based on response reactions and unity bond index–quadratic exponential potential (UBI–QEP) method;Surface Science;1999-06

4. On the use of response reactions in the kinetic modeling of complex heterogeneous catalytic reactions;Studies in Surface Science and Catalysis;1999