Affiliation:
1. Department of Chemistry, Semnan University , Semnan 3535119111 , Iran
Abstract
Abstract
In this work, magnetic nanoparticle-supported sulfonic acid (γ-Fe2O3-SO3H) is used as an efficient catalyst in the synthesis of 2,4,5-trisubstituted imidazoles and 1,2,4,5-tetrasubstituted imidazoles in a short time (40–70 min for trisubstituted imidazoles and 30–40 min for tetrasubstituted imidazoles) and high-purity products were obtained (92–98% for trisubstituted imidazoles and 94–98% for tetrasubstituted imidazoles) in simple multicomponent reactions. The structure of these products was confirmed via FT-IR and NMR. Green and recyclable catalysts, eco-friendly and solvent-free conditions, high catalytic activity, shorter reaction time, easy recovery by an external magnet, high purity, and excellent yields are some features of these reactions.
Reference35 articles.
1. Vaidya N. Toxicity focus is essential for green chemistry adoption and sustainable product development. Sustain Chem Pharm. 2019;11:12–6.
2. Marco BAd, Rechelo BS, Tótol EG, Kogawa AC, Salgado HRN. Evolution of green chemistry and its multidimensional impacts: a review. Saudi Pharm J. 2019;27(1):1–8.
3. Akbarzadeh P, Koukabi N. Fibroin-functionalized magnetic carbon nanotube as a green support for anchoring silver nanoparticles as a biocatalyst for A3 coupling reaction. Appl Organometal Chem. 2019;34(3). 10.1002/aoc.5395.
4. Albadi J, Samimi HA, Momeni AR. Alumina-supported cobalt nanoparticles efficiently catalyzed the synthesis of chromene derivatives under solvent-free condition. Chem Methodolog. 2020;4:565–71.
5. Maria A, Vincent MV, Mookkaiah R, Subramani R, Nadesan K. Catharanthus roseus leaf extract mediated facile green synthesis of copper oxide nanoparticles and its photocatalytic activity. Chem Methodolog. 2020;4(4):424–36.
Cited by
9 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Development of a new heterogeneous catalyst based on triple superphosphate for the one-pot multicomponent synthesis via green strategy, accompanied by a critical assessment of environmental sustainability metrics applied to the synthesis of 2,4,5-tri and 1,2,4,5-tetra substituted imidazole heterocycle derivatives;Journal of Molecular Structure;2024-12
2. Green synthesis of imidazoles: The catalytic efficacy of magnetic nanoparticles;Tetrahedron;2024-11
3. Nanostructured Iron (III)-Copper (II) Binary Oxide as a Highly Efficient
Magnetically Recoverable Nanocatalyst for Facile One-pot Synthesis of 2,
4, 5-trisubstituted Imidazole and 1, 4-dihydro Pyridine Derivatives under
Solvent-free Conditions;Letters in Organic Chemistry;2024-08
4. TiO2 nanoparticles as reusable catalysts for the efficient synthesis of 2, 4, 5-trisubstituted-1H-imidazoles;Journal of Physics: Conference Series;2024-05-01
5. Synthesis and application of MIL-101-NH2-CC/Melamine@Co2+ as a heterogeneous catalyst for preparation of 2,4,5-trisubstituted imidazoles and reduction of methylene blue;Research on Chemical Intermediates;2024-03-16