Uber die Reaktionen von Molekülen (R2CS)2 (R = CF3, CI) und Cl2CS mit XeF+MF6 - (M = As, Sb) und Kristallstruktur von [1] / On the Reactions of Molecules (R2CS)2 (R = CF3, Cl) and Cl2CS with XeF+MF6 - (M = As, Sb) and Crystal Structure of (CF3) [1]

Abstract

XeF+MF6 - (M = As, Sb) reacts with ((CF3)2CS)2 and Cl2CS to form the corresponding monofluorinated sulfonium hexafluorometalates. The salts have been characterized by vibrational and 19F NMR spectroscopic measurements. crystallizes in the monoclinic space group C2/c with a =o 14.791(10), b = 11.093(6), c - 10.356(6)Å, β = 119.83° and Z = 4. With a value of 1.51(1) Å d (S-F) is comparable to the SF-bond distance in .