Die Kristallstruktur von TIZnPO4 und TIZnAsO4 / The Crystal Structure of TIZnPO4 and TIZnAsO4

Author:

Andratschke Martina1,Range Klaus-Jürgen2,Weigl Claudia2,Schießl Ulrike2,Rau Franz2

Affiliation:

1. Institut für Anorganische und Analytische Chemie der Friedrich-Schiller-Universität Jena, August-Bebel-Straße 2. D-07743 Jena

2. Institut für Anorganische Chemie der Universität Regensburg, Universitätsstraße 31. D-93040 Regensburg

Abstract

Single crystals of the title com pounds were obtained by high pressure synthesis in a modified Belt type apparatus. The compounds crystallize in the monoclinic system (space group P21) with a = 8.732(2), b = 5.468(1), c = 8.841(2) Å, β = 90.61(2)° for TlZnPO4 and a = 8.921(3), b = 5.631(1), c = 8.958(3) Å, β = 91.03(2)° for TlZnAsO4, Z = 4. The structures were refined from diffractom eter data to R = 0.072, Rw = 0.050 for 3700 (TlZnPO4) and to R = 0.093, Rw = 0.067 for 3943 (TlZnAsO4) independent absorption corrected reflections. The compounds are isotypic and belong to the “stuffed derivatives" of the Icmm structure type with a (ZnXO4)- network of alternating corner linked ZnO4 and XO4 tetrahedra (X = P, As) forming channels of six-membered rings in the direction of the a axis. These cavities contain two crystallographically independent Tl cations in an irregular coordination by eight nearest oxygen atoms

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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