Affiliation:
1. Department of Chemistry, The Open University, Walton Hall, Milton Keynes, MK7 6AA , UK
2. Department of Chemistry, Christopher Ingold Laboratories, University College London,20 Gordon Street, London, WC 1 H 0 AJ, UK
Abstract
Initiation of the reaction between Na 3E (E = As, Sb, Bi) and anhydrous metal halides at 25 to 550 °C produces metal arsenides MxAsy (M=Y,La, Ti, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Co, Ni, Pt ,Cu and Zn) and antimonides MxSby (M=Ti, V, Nb, Ta, Cr, Fe, Co, Ni, Pt, Cu and Zn) via an exothermic selfpropagating reaction. The metal arsenides were characterized by X-ray powder diffraction, SEM/EDAX , microanalysis and FT-IR.
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19 articles.
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