Affiliation:
1. Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Alarich-Weiss-Straße 8, 64287 Darmstadt, Germany
Abstract
Abstract
The UV-VIS absorption spectra of (Ag1-X[Li-Cs, Ba]X)Cl and of (Ag1-X[Na, K, Cs]X)Br at 823 K at the concentrations X=0.0, 0.1, 0.2 have been measured. The findings show that on adding the respective halides to molten silver chloride and silver bromide, shifts of the fundamental absorption edge to shorter wavelengths result. A correlation between the observed shifts and the expansion of the silver sub-lattice is found, which is valid for both silver halide systems studied in this work.
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics
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