Nuclear Quadrupole Resonance Study of 35Cl in Chloral Hydrate, CCl3CH(OH)2, and Chloral Deuterate, CCl3CH(OD)2

Author:

Biedenkapp Dieter1,Weiss Alarich1

Affiliation:

1. Eduard-Zintl-Institut der Technischen Hochschule Darmstadt

Abstract

The nuclear quadrupole resonance (NQR) spectra of 35Cl in chloral hydrate and chloral deuterate were investigated in the temperature range between 77°K and 323 °K. Two modifications have been found for each substance. One of the modifications is unstable at room temperature and changes within a few weeks into the stable modification. The NQR spectrum can be explained in terms of crystal field effects.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Cited by 17 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Study of the polymorphic states of chloral hydrate by 35Cl NQR relaxometry;Chemical Physics Letters;2020-07

2. NQRS Data for C2H3Cl3O2 (Subst. No. 0538);Landolt-Börnstein - Group III Condensed Matter;2010

3. Applications of nuclear quadrupole resonance spectroscopy in drug development;Expert Opinion on Drug Discovery;2007-02

4. Study of γ-irradiated chloral hydrate single crystal by electron spin resonance;Journal of Molecular Structure;1990-11

5. Crystal Structure and Nuclear Quadrupole Resonance. The Bond Length C - Cl and 35Cl NQR;Berichte der Bunsengesellschaft für physikalische Chemie;1990-04

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