Dynamics of Water in Crystal Hydrates

Author:

Berthold Ingo1,Weiss Alarich1

Affiliation:

1. Eduard-Zintl-Institut der Technischen Hochschule Darmstadt, Lehrstuhl für Physikalische Chemie

Abstract

The 1H-NMR spectra of Na2S2O62 H20 and Li2S2Oe· 2 H20 single crystals have been investi-· gated at room temperature. The influence on the NMR spectra by the dynamical behaviour of the water molecules is discussed. The direction cosines of the different p—p lines were determined with a modified PAKE formula given by PEDERSEN. The parameters of the librational motions of the water molecules were calculated by the help of infrared data. The equilibrium H —H-distance in the water molecules was found to be 1.52 A.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

Cited by 7 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. A PMR study of the mobility of the water molecules in oxalic acid dihydrate;Journal of Structural Chemistry;1978

2. Nuclear Magnetic Resonance in Solid-State Chemistry;Angewandte Chemie International Edition in English;1972-07

3. Kernmagnetische Resonanz in der Festkörperchemie;Angewandte Chemie;1972-06

4. Molecular Motion and Structure around the Hydrated Ions Li+and Al3+;Berichte der Bunsengesellschaft für physikalische Chemie;1971-11

5. Nuclear Magnetic Resonance and the Mobility of Water in CsMnCl3·2H2O;The Journal of Chemical Physics;1971-07

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