Gas-Solid Interaction: Study of the Systems C6H6—γ-Αl2Ο3, CCl4—γ-Αl2Ο3 and cyclo-C6H12—γ-Αl2Ο3 by Means of the B.D.D.T. Equation

Author:

Sanesi Manlio1,Wagner Vittoriano1

Affiliation:

1. Institute of Physical Chemistry of the University, Pavia, Italy

Abstract

Gas-solid adsorption was experimentally investigated at 25°C for the title systems, which all exhibit isotherms of type IV with a hysteresis loop. The B.D.D.T. equation was employed for the treatment of the experimental data, and the values obtained for its four constants have been discussed and compared with values derived by independent methods. In particular, for C6H6—γ-Al2O3 a good agreement was found between the calculated value of the interaction energy in monolayer and calorimetric data.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy,Mathematical Physics

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