A new 2D dibutyltin coordination polymer with 3,5-dinitrosalicylate and 4,4’-bipyridine ligands

Author:

Tian Laijin1,Wang Ruili1,Zhang Jiawei1,Liu Qingtao1

Affiliation:

1. Key Laboratory of Natural Products and Pharmaceutical Intermediates, Qufu Normal University , Qufu , China

Abstract

Abstract A new 2D dibutyltin coordination polymer with 3,5-dinitrosalicylate and 4,4’-bipyridine ligands, [{Bu2Sn(3,5–(NO2)2–2–OC6H2COO)}2(4,4’-bpy)]n (1), has been synthesized and characterized both spectroscopically (IR, 1H, 13C, and 119Sn NMR) and a single-crystal X-ray diffraction analysis. The coordination geometry of tin atom in 1 is a distorted octahedron. 3,5-Dinitrosalicylate as doubly charged anion ligand adopts chelating-bridging mode to coordinate to tin atoms, and 4,4’-bipyridine further bridges the tin atoms to form a 2D herringbone-like network structure containing the 34-membered hexa-nuclear macrocycles.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Metals and Alloys,Condensed Matter Physics,General Chemistry

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