Synthesis and structural characterization of a novel lead dinuclear complex: [Pb(L)(I)(sba)<sub>0.5</sub>]<sub>2</sub>-Reference-Cited by-同舟云学术

Synthesis and structural characterization of a novel lead dinuclear complex: [Pb(L)(I)(sba)_0.5]₂

Published:2022-01-01 Issue:1 Volume:45 Page:213-218
ISSN:2191-0219
Container-title:Main Group Metal Chemistry
language:en
Short-container-title:

Author:

Wang Xiuyan¹²,Li Ziru¹²,Wang Jie²,Zhao Lina¹²

Affiliation:

1. Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Ministry of Education , Changchun 130103 , China

2. Department of Chemistry, Jilin Normal University , Siping 136000 , China

Abstract

Abstract A new two-dimensional (2D) metal–organic complex, [Pb(L)(I)(sba)0.5]2 (1, L = 2-(2,4-difluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline, H2sba = suberic acid), was synthesized under hydrothermal conditions. The single-crystal X-ray analysis indicates that the asymmetric unit of complex 1 has a distorted [:PbIN2O2] octahedral geometry. It is further extended by two π–π stacking interactions and N–H⋯O hydrogen bonding to form and stabilize 2D supramolecular layer.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Metals and Alloys,Condensed Matter Physics,General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/mgmc-2022-0022/pdf

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