Synthesis and structural characterization of a novel lead coordination polymer: [Pb(L)(1,3-bdc)]·2H2O

Author:

Li Ziru12,Zhao Jiaqi2,Lou Meiqi2,Wang Xiuyan12

Affiliation:

1. Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Ministry of Education , Changchun 130103 , China

2. Department of Chemistry, Jilin Normal University , Siping 136000 , China

Abstract

Abstract A novel coordination polymer, [Pb(L)(1,3-bdc)]·2H2O (1), (L = 2-(2,6-dichlorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline, 1,3-H2bdc = 1,3-benzenedicarboxylic acid) has been successfully prepared under hydrothermal conditions. The structure of 1 is a 1D chain structure, which further stacks together to form a 3D supramolecular architecture by π–π interactions and C–H⋯π interactions. In addition, the thermogravimetric analysis of 1 has been investigated.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Metals and Alloys,Condensed Matter Physics,General Chemistry

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