Thermodynamics of transamination reactions with aminotrimethylsilanes and diaminodimethylsilanes

Abstract

Abstract Transamination reactions of two different aminosilanes (trimethyl(tert-butylamino)silane and dimethyl(diamino)silane) with amines (diethylamine, pyrrolidine, tert-butylamine, iso-propylamine, and n-propylamine) are studied. For trimethyl(organoamino)silanes, the reaction of trimethyl(iso-propylamino)- or trimethyl(diethylamino)silane as aminosilanes and aniline or pyrrolidine are good starting materials to produce trimethyl(anilino)- and trimethyl(pyrrolidino)silane. The investigated equilibrium constants of the reactions of monoaminosilanes show a good correlation with quantum chemically calculated values. The reaction of two different diaminosilanes Me2Si(NR1R2)2 and Me2Si(NR3R4)2 containing different amino moieties leads to the formation of mixed diaminosilanes Me2Si(NR1R2)(NR3R4) in most cases.