Affiliation:
1. Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Ministry of Education , Changchun 130103 , China
2. Department of Chemistry, Jilin Normal University , Siping 136000 , China
Abstract
Abstract
A new Cd(ii) coordination polymers, formulated as [Cd(1,4-chdc)(L)]
n
(1) (L = 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol ligands and 1,4-H2chdc = 1,4-cyclohexanedicarboxylate acid), were successfully synthesized by using L ligand and 1,4-H2chdc acid under hydrothermal conditions and characterized by single crystal X-ray elemental analyses, diffraction, and IR spectroscopy. Each Cd(ii) atom is a distorted pentagonal bipyramidal geometry connecting the deprotonated 1,4-chdc anion to form a 2D layer, and a 2D layer is formed into a 3D supramolecular structure by the π–π stacking interactions between neighboring layers.
Subject
Materials Chemistry,Metals and Alloys,Condensed Matter Physics,General Chemistry
Cited by
2 articles.
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