A new cadmium(ii) coordination polymer with 1,4-cyclohexanedicarboxylate acid and phenanthroline derivate: Synthesis and crystal structure-Reference-Cited by-同舟云学术

A new cadmium(ii) coordination polymer with 1,4-cyclohexanedicarboxylate acid and phenanthroline derivate: Synthesis and crystal structure

Published:2022-01-01 Issue:1 Volume:45 Page:208-212
ISSN:2191-0219
Container-title:Main Group Metal Chemistry
language:en
Short-container-title:

Author:

Su Beihao¹²,Shi Yihan²,Peng Xuehan²,Kong Zhiguo¹²,Chang Limin¹²

Affiliation:

1. Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Ministry of Education , Changchun 130103 , China

2. Department of Chemistry, Jilin Normal University , Siping 136000 , China

Abstract

Abstract A new Cd(ii) coordination polymers, formulated as [Cd(1,4-chdc)(L)] n (1) (L = 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol ligands and 1,4-H2chdc = 1,4-cyclohexanedicarboxylate acid), were successfully synthesized by using L ligand and 1,4-H2chdc acid under hydrothermal conditions and characterized by single crystal X-ray elemental analyses, diffraction, and IR spectroscopy. Each Cd(ii) atom is a distorted pentagonal bipyramidal geometry connecting the deprotonated 1,4-chdc anion to form a 2D layer, and a 2D layer is formed into a 3D supramolecular structure by the π–π stacking interactions between neighboring layers.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,Metals and Alloys,Condensed Matter Physics,General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/mgmc-2022-0020/pdf

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