Affiliation:
1. Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University , Guiyang 550025 , China
Abstract
Abstract
Herein, we report the supramolecular complexes of cyclohexanocucurbit[6]uril (CyH6Q[6]) with Cu(ClO4)2, Zn(ClO4)2, and Mg(ClO4)2 in formic acid solution. The crystal structure was determined using single crystal X-ray diffraction. The analysis results showed that CyH6Q [6] formed a one-dimensional supramolecular chain with Cu(ClO4)2 and formed a supramolecular assembly with a mixture ratio of 2:3 with Zn(ClO4)2 and Mg(ClO4)2. In this system,
ClO
4
−
{\text{ClO}}_{4}^{-}
induced CyH6Q[6] and metal ions to form supramolecular complexes through ion–dipole interactions.
Subject
Health, Toxicology and Mutagenesis,Industrial and Manufacturing Engineering,Fuel Technology,Renewable Energy, Sustainability and the Environment,General Chemical Engineering,Environmental Chemistry
Cited by
3 articles.
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