Affiliation:
1. School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, P.R. China
2. School of Petrochemical Engineering, Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Changzhou University, Changzhou 213164, P.R. China
Abstract
Abstract
Two isostructural fluorinated metal-organic frameworks, formulated as [M
2(Fbix)(1,4-NDC)2]
n
(M=Cd for 1 and Mn for 2), were synthesized by employing 1,4-naphthalenedicarboxylic acid (1,4-H2NDC) and the flexible fluorinated ligand 2,3,5,6-tetrafluoro-1,4-bis(imidazole-1-yl-methyl)benzene (Fbix) under hydrothermal conditions. Their structures were determined by single-crystal X-ray diffraction and further characterized by infrared spectroscopy, powder X-ray diffraction, and thermogravimetric analyses. Structure analyses have revealed that compounds 1 and 2 show an unusual hex net based on infinite rod-shaped secondary building units. The solid-state fluorescence spectra of 1 and 2 were measured and indicate a ligand-based emission for both complexes.
Cited by
2 articles.
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