Synthesis, crystal structure and Raman spectrum of Ba7[BO3]3Br(O1.33F1.33)-Reference-Cited by-同舟云学术

Synthesis, crystal structure and Raman spectrum of Ba7[BO3]3Br(O1.33F1.33)

Published:2017-01-20 Issue:3 Volume:72 Page:193-197
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Reckeweg Olaf¹,Schulz Armin²,DiSalvo Francis J.³

Affiliation:

1. Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA , Fax:+1-607-255-4137

2. Max-Planck-Institut für Festkörperforschung, Heisenbergstraße 1, D-70569 Stuttgart, Germany

3. Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA

Abstract

Abstract In addition to amorphous material and Ba7[BO3]4−x F2−3x , air and moisture sensitive single crystals of Ba7[BO3]3Br(O1.33F1.33) were formed from H3BO3, Ba(OH)2, BaF2 and BaBr2·2 H2O in alumina crucibles open to the atmosphere at 1300 K for 13 h. Ba7[BO3]3Br(O1.33F1.33) crystallizes in the hexagonal space group P63 mc (no. 186, Z=2) with the lattice parameters a=1118.1(2) and c=723.93(13) pm. The Raman spectrum of the title compounds was also acquired and is compared to literature data.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2016-0243/pdf

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