Affiliation:
1. Institut für Anorganische und Analytische Chemie , Universität Münster , Corrensstrasse 30, 48149 Münster, Germany
2. Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB) , CNRS [UPR 9048], Université de Bordeaux , Avenue du Docteur A. Schweitzer, 33608 Pessac Cedex, France
Abstract
Abstract
Intermetallic compounds with the equiatomic composition CeTX that crystallize with the orthorhombic TiNiSi-type structure can be synthesized with electron-rich transition metals (T) and X = Zn, Al, Ga, Si, Ge, Sn, As, Sb, and Bi. The present review focusses on the crystal chemistry and chemical bonding of these CeTX phases and on their physical properties, 119Sn and 121Sb Mössbauer spectra, high-pressure effects, hydrogenation reactions and the formation of solid solutions in order to elucidate structure–property relationships. This paper is the final one of a series of four reviews on equiatomic intermetallic cerium compounds [Part I: Z. Naturforsch. 2015, 70b, 289; Part II: Z. Naturforsch. 2015, 70b, 695; Part III: Z. Naturforsch. 2016, 71b, 165].
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