Synthesis and Structural Characterization of the Mixed Ligand Complex [Cu(Hml)2(Phen)] · 2 H2O (H2ml = 2-Methyllactic Acid)-Reference-Cited by-同舟云学术

Synthesis and Structural Characterization of the Mixed Ligand Complex [Cu(Hml)2(Phen)] · 2 H2O (H2ml = 2-Methyllactic Acid)

Published:2003-01-01 Issue:1 Volume:58 Page:151-154
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Carballo Rosa¹,Covelo Berta¹,Vázquez-Lópeza Ezequiel M.¹,Castiñeiras Alfonso²,Niclós Juan³

Affiliation:

1. Universidade de Vigo, Departamento de Química Inorgánica, Facultade de Ciencias, E-36200 Vigo, Galicia, Spain

2. Universidade de Santiago de Compostela, Departamento de Química Inorgánica, Facultade de Farmacia, E-15782 Santiago de Compostela, Galicia, Spain

3. Universidad de Granada, Departamento de Química Inorgánica, Facultad de Farmacia, E-18071 Granada, Spain

Abstract

Abstract A new mixed-ligand complex of copper(II) with 1,10-phenanthroline and 2-methyllactate was prepared. [Cu(HmL)2(phen)] ·2H2O (where HmL = monodeprotonated 2-methyllactic acid) was characterized by elemental analysis, IR, electronic and EPR spectroscopy, magnetic measurements at room temperature, thermogravimetric analysis and X-ray diffractometry. The copper atom is in a tetragonally distorted octahedral environment and the 2-methyllactato ligand is bidentately chelating. The presence of lattice water molecules mediates the formation of a three-dimensional network.

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-2003-0122/pdf

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