Photolysis of Naphthol Green B in Aqueous Solution. Photoreduction of Fe(III) Induced by Ligand-to-Metal Charge Transfer Excitation

Abstract

The intense long-wavelength absorption of Naphthol Green B at λmax = 712 nm is assigned to a ligand-to-metal charge transfer (MLCT) transition. LMCT excitation of the complex in aqueous solution leads to the reduction of Fe(III) to Fe(II) with a quantum yield of ϕ = 1.14×10−3 at λirr = 577 nm.