Neue mixed-valence-Verbindungen mit Sb(III) und Sb(V) vom Typ (RH+)8(C1-)4SbCl6 3- SbCl6 - / New Mixed-valence Compounds with Sb(III) and Sb(V) of the Structure (RH+)8(Cl-)4SbCl6 3-SbCl6 --Reference-Cited by-同舟云学术

Neue mixed-valence-Verbindungen mit Sb(III) und Sb(V) vom Typ (RH+)8(C1-)4SbCl6 3- SbCl6 - / New Mixed-valence Compounds with Sb(III) and Sb(V) of the Structure (RH+)8(Cl-)4SbCl6 3-SbCl6 -

Published:1979-08-01 Issue:8 Volume:34 Page:1059-1063
ISSN:1865-7117
Container-title:Zeitschrift für Naturforschung B
language:en
Short-container-title:

Author:

Eisinger H. K.¹,Latscha H. P.¹

Affiliation:

1. Anorganisch-Chemisches Institut der Universität Heidelberg, Im Neuenheimer Feld 270, D-6900 Heidelberg

Abstract

New mixed-valence-compounds with Sb(III) and Sb(V) of the structure (RH+)8(Cl-)4SbCl6 3-SbCl6 - with R equal CH3CH(NH2)CH3, CH3CH(NH2)CH2CH3, CH3CH2CH2NH2,

and CH3CH(CH2NH2)CH3 are reported. Different methods of preparation for these compounds are described. Compounds with the structure (RH+)8(Br-)4SbCl6 3-SbCl6 - are obtained with R = CH3CH(NH2)CH2CH3 and CH3CH(NH2)CH3. All compounds are characterised, their formation is discussed

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/znb-1979-0804/pdf

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