Affiliation:
1. Institut für Anorganische Chemie der Universität München, Meiserstraße 1, D-8000 München 2
Abstract
Abstract
Proton addition to the spirobi(cyclotriphosphazene) anion 1 gives the neutral species 2. An X-ray structure determination shows the proton to be located at a nitrogen atom next t o the spirocenter. The structural consequences of this protonation can be demonstrated by comparisons of intramolecular bond distances and angles and can be understood in terms of structure-determining repulsive N/N interactions in the central PN4 unit
Cited by
10 articles.
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