Tetrakis(trimethylsilyl)distiban / Tetrakis (trimethylsilyl) distibane

Author:

Breunig Hans Joachim1,Breunig-Lyriti Vassiliki1

Affiliation:

1. Universität Bremen, Postfach 330440, D-2800 Bremen 33

Abstract

Abstract Tetrakis(trimethylsilyl)distibane, (Me3Si)4Sb2 is produced by reaction of tris(trimethylsilyl) stibine, (Me3Si)3Sb, with three or less than three equivalents of t-butyl iodide, with trimethyliodosilane, Me3SiI and iodine. The reaction of (Me3Si)3Sb with three or more equivalents of i-butyl iodide and methyl iodide also yields tri-t-butylstibine, trimethylstibine and Me3SiI

Publisher

Walter de Gruyter GmbH

Subject

General Chemistry

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5. Crystal structures of tris(trimethylsilyl)stibine and pentacarbonyl(tris(trimethylsilyl)stibine)chromium;Journal of Organometallic Chemistry;2000-08

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