Affiliation:
1. Abteilung II für Anorganische Chemie im Eduard-Zintl-Institut der Technischen Hochschule in Darmstadt, Hochschulstraße 4, D-6100 Darmstadt
Abstract
Cs2Sb8S13 has been prepared and its structure determined. It crystallizes in the triclinic system P1̄ with
a = 1543.7(5) pm, b = 1148.8(4) pm, c = 829.9(4) pm;
α = 71.89(5)°, β = 102.45(5)°, γ = 95.16(5)°.
SbS3-ψ-tetrahedra and SbS4-ψ-trigonal bipyramids are connected together to sheets, separated by Cs ions.
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